The sampling duration was 2 h with 12 atmospheric samples collected each day: 00:00-02:00; 02:00-04:00; 04:00-06:00; 06:00-08:00; 08:00-10:00; 10:00-12:00; 12:00-14:00; 14:00-16:00; 16:00-18:00; 18:00-20:00; 20:00-22:00; 22:00-00:00. One aspect of the figure is of interest, two large increases were observed in HCHO in the early morning and after dusk. Our latest podcast episode features popular TED speaker Mara Mintzer. Be on the lookout for your Britannica newsletter to get trusted stories delivered right to your inbox. Other aldehydes of industrial significance are mainly used as solvents, perfumes, and flavouring agents or as intermediates in the manufacture of plastics, dyes, and pharmaceuticals. and will receive updates in the daily or weekly email digests if turned on.

Ambient carbonyls were collected on silica cartridges coated with acidified DNPH (IC-DN3501, Agela Technologies, China). These compounds are reported to be insoluble in water but sometimes they dissolve other forms of polar molecules. These results suggested that anthropogenic sources around the site had considerable contributions in addition to the contribution of photochemical reactions during the day. When the carbonyl carbon is bonded to one alkyl/aryl group and one OH group, the resulting carbonyl compound can be classified as carboxylic acid and its chemical formula can be generalized to R-COOH. In addition, from May 12 to 20, the GSS site showed large diurnal variations in the concentrations of O3 and the carbonyl compounds, and these concentrations peaked at almost the same time (around noon), which indicated that photochemical reactions were the main contributor to O3 and carbonyl compound formation during the day at the GSS site. It is well-known that atmospheric photochemical reactions are one of the important production routes of carbonyl compounds in ambient air and an important method of O3 generation.

These classes of organic compoundscontain a carbonyl functional group (C=O) with structures CHO for aldehydes and RC(=O)R’ for ketones. The concentration at the urban site was 15.45 ± 11.18 ppbv and the concentration at the suburban site was 17.57 ± 12.77 ppbv. During the observation period, the daily change in the O3 concentration at the GSS site also showed a single peak, and the trend was similar to that observed for the carbonyl compounds. The toxicities of ketones and esters are similar to those of aldehydes in…, between ketones (or aldehydes) and their enol forms, which contain a hydroxyl group directly attached to a doubly bonded carbon atom:…. The GSS site was located in a forested area and there was one main source of carbonyl compounds. Generally, the A/P ratio can be used to indicate the presence of man-made pollutants because propionaldehyde is considered only to be associated with anthropogenic sources (Shepson et al., 1991). In addition, certain aldehydes perform essential functions in humans and other living organisms.

Because oxygen is more electronegative than carbon, carbonyl compounds often have resonance structures which affect their reactivity. On May 19 and 20, the temperature dropped and the wind direction changed, which resulted in decreases in the concentrations of carbonyl compounds at the two sites. Acetone released from various sources accumulates in the atmosphere (Atkinson, 2000; Dai et al., 2012) , and the most important sources are natural sources (Janson & Serves, 2001), with pine trees accounting for a higher share of emissions. Formaldehyde is used in the manufacture of plastics and also it is used in the biological laboratories for preservation purposes. The simulated distribution of HCHO from photochemical production was compared with the observed HCHO concentration. Blank samples were collected by passive sampling, which involved opening a sealed cartridge and placing it in the ambient air at the same time as a cartridge was used for active air sampling.

Among the anthropogenic sources, motor vehicle exhaust emissions are more significant (Janson & Serves, 2001).

After sampling, the cartridges were sealed with Teflon caps immediately, placed in an aluminum foil bag to protect them from light, and stored in a refrigerator (<4 °C). The F/A and A/P ratios were used to determine the sources of the carbonyl compounds. Two cartridges in series were sampled to evaluate the collection efficiency before application to the first sample collection in the field. The sampling and analysis procedures used were based on the Environmental Protection Agency method TO-11A (US EPA, 1999). When the carbonyl group is linked to one alkyl or aryl group and one hydrogen atom, the resulting carbonyl compound is called an aldehyde. The separation column was a Inertsil ODS-P reversed-phase column (250 × 4.6 mm i.d., 5 µm particle size; Shimadzu, Japan) at 40 °C. They are mainly formed by the oxidation of biogenic and anthropogenic hydrocarbons (Zhu et al., 2019), and are also directly emitted from natural and anthropogenic sources (Singh et al., 1995; Wu & Wang, 2015; Xiang et al., 2017; Zarzana et al., 2017). The high concentrations of carbonyl compounds may be important contributors to serious atmospheric photochemical pollution in Chinese cities. HCHO, acetaldehyde, and acetone were the main species in Fuzhou city, and acetone had the highest concentration. Propionaldehyde is mainly related to anthropogenic emissions, and acetaldehyde may come from secondary generation or primary emission. Two filed blank samples were collected both before and after the sampling process. Hence, these are said to be polar molecules. 1). They are said to be the lovers of nuclei such as the bases. The sources of carbonyl compounds can be roughly determined from the ratio of the concentrations of atmospheric formaldehyde/acetaldehyde (F/A) to that of acetaldehyde/propionaldehyde (A/P) (Shepson et al., 1991). The intensity of solar radiation directly affects reaction rates in atmospheric photochemistry. The results of an observation-based model showed that anthropogenic hydrocarbons promoted HCHO production on May 17 at the urban site. The site was surrounded by residential areas and was considered a typical urban site with no pollution sources. The resulting change in molecular geometry is responsible for generating a nerve impulse that is sent to the brain and perceived as a visual signal (see also photoreception). Two observation sites were chosen on the rooftop of the Jinjishan Environmental Protection Building (Jijishan site: JJS) and in the Gushan Scenic Area (Gushan site: GSS) in the suburbs of Fuzhou, China (Fig. We All VOCs species were categorized as biogenic or anthropogenic hydrocarbons (AHCs). The O3 concentrations were measured by a UV photometric O3 analyzer (Model 49i, Thermo Fisher Scientific, USA). Diurnal variation at the JJS site was different to that at the GSS site. It is typically applied to the root systems of over 40 different crops. From May 14 to 17, the concentration of acetaldehyde decreased and that of acetone increased rapidly. Over 98% of carbonyls were detected in the first cartridge. Suburban areas with high vegetation coverage had high F/A values, whereas urban areas were greatly affected by human activities and the A/P values were higher. Among these are benzaldehyde, which provides the odour and flavour of fresh almonds; cinnamaldehyde, or oil of …

From May 15 to 18, the concentration of acetone increased rapidly and it became the main species, followed by acetaldehyde and HCHO, and the concentrations of the compounds continued to increase. Detection information of 16 carbonyl compounds by HPLC/UV. The JJS site was located 30 m above the ground at the foot of the southwest Jinjishan mountain in the Jin’an district, Fuzhou. Other carbonyl compounds of industrial use. Ketones are carbonyl compounds in which the carbonyl carbon is linked to two alkyl or aryl groups.

Baker, USA). During the day, the carbonyl compounds showed a peak at 07:00, concentrations then rose from 05:00 to 07:00 before decreasing slightly from 07:00 to 09:00. From May 18 to 20, the total concentration of carbonyl compounds declined as the acetone concentration decreased. The GSS site was located on the top of the Songtao Building of the Gushan Scenic Area Management Committee. 8). The extracts were then analyzed by HPLC (LC20A, Shimadzu, Japan) with UV-Vis detection at 360 nm. From May 8 to 14, the JJS site was similar to the GSS site and the carbonyl compound concentration was relatively low. The study was continuously carried out at an urban site (Jinjishan) and a suburban site (Gushan) in Fuzhou from May 8 to 20, 2018. Samples were collected at a 2 h intervals beginning at 00:00 (UTC+8) from May 8 to 20, 2018. Fuzhou is a city with relatively good air quality in China, ranking 6th out of 168 key cities in China for ambient air quality in 2019. Figure 2 shows the measured time series of major carbonyl compounds, O3, NO2, SO2, CO, PM2.5, and meteorological parameters at the JJS and GSS sites in Fuzhou from May 8 to 20, 2018. The F/A values were slightly higher at night than during the day at both sites, which could be attributed to the fact that formaldehyde and acetaldehyde were removed at night mainly by reactions with NO3 radicals. the lone pair electrons of nitrogen in the ammoniamolecule). Fuzhou is in the western part of the Taiwan Strait and is subject to weaker winds during the monsoon exchange period in May and is less affected by regional transmission. Fuzhou is located on the southeast coast of China. These results were comparable to the acetone concentrations measured by Yang et al. However, there were some arguments that the ratios of F/A and A/P often have large variations due to different sources of pollution and meteorological conditions (Grosjean, 1992; Ho et al., 2015), thus we should use it with caution. During the observation period, the F/A value at the JJS site (daytime: 0.18–0.69, nighttime: 0.10–1.43) also first decreased and then increased. Alfa Chemistry can offer a wide variety of carbonyl compounds including alcohols, amino alcohols, epoxides, ethers, ortho esters, and phenols. Figure 3 shows diurnal variation of the total carbonyl compound and O3 concentrations at the GSS and JJS sites from May 18 to 20, 2018. Fifty-seven VOCs species of Photochemical Assessment Monitoring Stations (PAMS) were identified using a gas chromatograph equipped with a flame ionization detector and a mass spectrometry detector (EPA/600-R-98/161, Technical Assistance Document for Sampling and Analysis of Ozone Precursors) at the same laboratory in Chinese Research Academy of Environmental Sciences. The authors declare there are no competing interests. It means that they control the reactions of a chemical reaction. Acetone was the most abundant carbonyl compound at the GSS and JJS sites, which could be attributed to its chemical stability and long atmospheric lifetime. Carbonyl compounds are precursors of O3 and secondary organic aerosols, and play key roles in the atmospheric photochemical oxidation cycle. Similar to the GSS site, the JJS site had higher concentrations of carbonyl compounds during the day than at night; however, the JJS site had much higher concentrations at night (19:00–07:00) than the GSS site, indicating a persistent source of pollution. The RIRs for the NOx were negative. In fact, many simulations showed that the concentration of OH radicals was highest in the afternoon during the day (Tan et al., 2019; Zong et al., 2018). The carbonyl compounds reactions are given below: Your email address will not be published. Most of the unhealthy symptoms induced by carbonyl compounds are irritation to the eyes and lungs (WHO, 2000). College of Resource and Environment Engineering, Guizhou University, State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Environment Research Institute, Shandong University, This is an open access article distributed under the terms of the.


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